I don't think it has been considered, and certainly not rejected. It's a good idea.
A lot of details can be discussed. There could be
Gtk::Container::add(std::initializer_list<Gtk::Widget*> widgets);
Gtk::Box::pack_start(std::initializer_list<Gtk::Widget*> widgets, PackOptions options);
Gtk::Box::pack_end(std::initializer_list<Gtk::Widget*> widgets, PackOptions options);
etc.
It would be even better with a list of references: std::initializer_list<Gtk::Widget&>. Is that possible, or would the compiler try to copy the widgets?